@article { author = {Parsafard, Nastaran and Peyrovi, Mohammad Hassan and Valipour Shokoohi, Mehrdad}, title = {Study of HMS Modified ZrO2 Supported Platinum Catalysts for Toluene Removal: Catalytic Combustion and Kinetics Study}, journal = {Physical Chemistry Research}, volume = {6}, number = {4}, pages = {721-728}, year = {2018}, publisher = {Iranian Chemical Society}, issn = {2322-5521}, eissn = {2345-2625}, doi = {10.22036/pcr.2018.141366.1508}, abstract = {Reaction behaviors and kinetics of catalytic oxidation of toluene with different feed flows over Pt/Zr(x)-HMS catalysts with Si/Zr ratio equal to 5, 10, 20 and 35 were investigated over a wide temperature range (200 – 500 oC). Results show that Pt/Zr(x)-HMS performs more easily toluene oxidation. The kinetic data were fitted by the Power-law and Mars–van Krevelen kinetic models. The fitting results show that the Mars–van Krevelen model (R2 > 0.99) is more suitable for predicting the conversion of toluene than the Power law model (R2 = 0.53), and the Mars–van Krevelen model can accurately express the reaction rate of this process.}, keywords = {Toluene oxidation,Kinetics,Conversion,Power law model,Mars-van Krevelen model}, url = {https://www.physchemres.org/article_67205.html}, eprint = {https://www.physchemres.org/article_67205_bf82eacd258f1435297e1e85f890758d.pdf} }