TY - JOUR ID - 50006 TI - N-Heterocyclic Plumbylenes (NHPbs) at Theoretical Levels JO - Physical Chemistry Research JA - PCR LA - en SN - 2322-5521 AU - Mohebi, Nazanin AU - Kassaee, Mohammad Zaman AD - Department of Chemistry, Tarbiat Modares University, P.O. Box 14115-175, Tehran, Iran Y1 - 2017 PY - 2017 VL - 5 IS - 4 SP - 819 EP - 830 KW - N-Heterocyclic plumbylenes KW - Nucleophilicity KW - Singlet-triplet energy gaps KW - Substituent effects KW - Density functional theory DO - 10.22036/pcr.2017.91172.1395 N2 - Plumbylenes are reactive intermediates whose discovery and characterizations are of great significance. Here, ten novel plumbylenes are introduced and characterised. A comparison is made between novel 1,4-di(R)tetrazol-5-plumbylenes (IR) with their corresponding 1,3-di(R) isomers (IIR), at DFT (R = H, Me, Et, i-Pro, and t-Bu). Every one of our plumbylenes (IR or IIR) appears less stable, with a lower band gap (ΔΕHOMO-LUMO), and a higher nucleophilicity (N) than its corresponding carbene (I´R or II´R). For both IR and IIR plumbylenes the trend of N values emerges consistent with the size of substituents (t-Bu > i-Pro > Et > Me > H). Every IIR shows a higher N than its corresponding IR. Except IIH, every IIR emerges more aromatic than its related IR. The N of both IR and IIR appears directly proportional to the size of R, proton affinity (PA), and plumbylene bond angles (N—((Pb) ̈ ) ̂—N); while it is inversely proportional to electrophilicity (ω), and ΔΕHOMO-LUMO. UR - https://www.physchemres.org/article_50006.html L1 - https://www.physchemres.org/article_50006_29e41f31e8044a2bce41d357d763fa6a.pdf ER -