Reaction behaviors and kinetics of catalytic oxidation of toluene with different feed flows over Pt/Zr(x)-HMS catalysts with Si/Zr ratio equal to 5, 10, 20 and 35 were investigated over a wide temperature range (200 – 500 oC). Results show that Pt/Zr(x)-HMS performs more easily toluene oxidation. The kinetic data were fitted by the Power-law and Mars–van Krevelen kinetic models. The fitting results show that the Mars–van Krevelen model (R2 > 0.99) is more suitable for predicting the conversion of toluene than the Power law model (R2 = 0.53), and the Mars–van Krevelen model can accurately express the reaction rate of this process.
Parsafard, N., Peyrovi, M. H., & Valipour Shokoohi, M. (2018). Study of HMS Modified ZrO2 Supported Platinum Catalysts for Toluene Removal: Catalytic Combustion and Kinetics Study. Physical Chemistry Research, 6(4), 721-728. doi: 10.22036/pcr.2018.141366.1508
MLA
Nastaran Parsafard; Mohammad Hassan Peyrovi; Mehrdad Valipour Shokoohi. "Study of HMS Modified ZrO2 Supported Platinum Catalysts for Toluene Removal: Catalytic Combustion and Kinetics Study". Physical Chemistry Research, 6, 4, 2018, 721-728. doi: 10.22036/pcr.2018.141366.1508
HARVARD
Parsafard, N., Peyrovi, M. H., Valipour Shokoohi, M. (2018). 'Study of HMS Modified ZrO2 Supported Platinum Catalysts for Toluene Removal: Catalytic Combustion and Kinetics Study', Physical Chemistry Research, 6(4), pp. 721-728. doi: 10.22036/pcr.2018.141366.1508
VANCOUVER
Parsafard, N., Peyrovi, M. H., Valipour Shokoohi, M. Study of HMS Modified ZrO2 Supported Platinum Catalysts for Toluene Removal: Catalytic Combustion and Kinetics Study. Physical Chemistry Research, 2018; 6(4): 721-728. doi: 10.22036/pcr.2018.141366.1508
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