Reaction behaviors and kinetics of catalytic oxidation of toluene with different feed flows over Pt/Zr(x)-HMS catalysts with Si/Zr ratio equal to 5, 10, 20 and 35 were investigated over a wide temperature range (200 – 500 oC). Results show that Pt/Zr(x)-HMS performs more easily toluene oxidation. The kinetic data were fitted by the Power-law and Mars–van Krevelen kinetic models. The fitting results show that the Mars–van Krevelen model (R2 > 0.99) is more suitable for predicting the conversion of toluene than the Power law model (R2 = 0.53), and the Mars–van Krevelen model can accurately express the reaction rate of this process.
Parsafard, N., Peyrovi, M., Valipour Shokoohi, M. (2018). Study of HMS Modified ZrO2 Supported Platinum Catalysts for Toluene Removal: Catalytic Combustion and Kinetics Study. Physical Chemistry Research, 6(4), 721-728. doi: 10.22036/pcr.2018.141366.1508
MLA
Nastaran Parsafard; Mohammad Hassan Peyrovi; Mehrdad Valipour Shokoohi. "Study of HMS Modified ZrO2 Supported Platinum Catalysts for Toluene Removal: Catalytic Combustion and Kinetics Study". Physical Chemistry Research, 6, 4, 2018, 721-728. doi: 10.22036/pcr.2018.141366.1508
HARVARD
Parsafard, N., Peyrovi, M., Valipour Shokoohi, M. (2018). 'Study of HMS Modified ZrO2 Supported Platinum Catalysts for Toluene Removal: Catalytic Combustion and Kinetics Study', Physical Chemistry Research, 6(4), pp. 721-728. doi: 10.22036/pcr.2018.141366.1508
VANCOUVER
Parsafard, N., Peyrovi, M., Valipour Shokoohi, M. Study of HMS Modified ZrO2 Supported Platinum Catalysts for Toluene Removal: Catalytic Combustion and Kinetics Study. Physical Chemistry Research, 2018; 6(4): 721-728. doi: 10.22036/pcr.2018.141366.1508