Mechano-Optical Study of the Deformation of Polymer Films

Document Type : Regular Article

Authors

1 Nanotechnology Development Center, National University of Uzbekistan, Tashkent, 100174 Republic of Uzbekistan. University of Public Safety of the Republic of Uzbekistan, Tashkent, 100109 Republic of Uzbekistan

2 Nanotechnology Development Center, National University of Uzbekistan, Tashkent, 100174 Republic of Uzbekistan

3 Institute of Chemistry and Physics of Polymers of the Academy of Sciences of the Republic of Uzbekistan, Tashkent, 100128 Republic of Uzbekistan

4 University of Public Safety of the Republic of Uzbekistan, Tashkent, 100109 Republic of Uzbekistan

10.22036/pcr.2023.392038.2319

Abstract

This article explores the insights provided by infrared (IR) spectroscopy into the optical properties and surface morphology of polyethylene (PE) polypropylene (PP), and polyvinyl chloride (PVC) films. Notably, IR spectroscopy can identify absorption lines attributed to various functional groups in addition to those associated with lower-density linear polyethylene. The specific characteristics of IR spectra for linear low density polyethylene are influenced by polymer processing conditions, branching, and monomer content. Moreover, the IR spectrum of PVC offers valuable information about its molecular structure and composition. Comparatively, polypropylene (PP) films exhibit higher absolute light transmission in the ultraviolet and visible spectrum when contrasted with films based on PE and PVC. The utilization of atomic force microscopy (AFM) and IR spectroscopy reveals that heat-induced decomposition and subsequent cooling do not impact the surface roughness or thickness of the films, confirming the retention of structural and electrophysical attributes.

Graphical Abstract

Mechano-Optical Study of the Deformation of Polymer Films

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