A semi-empirical equation of state has been studied for modelling vapour-liquid data of pure substances. The specific molecular based equation of state is employed here as basis because of its mathematical simplicity. The semi-empirical extension has been accomplished to real fluids by correlating the density dependence of the attraction term to vapour liquid data of a reference fluid. The resulting attraction term is mathematically relatively simple and fulfills the topological requirements given by the physical background. With this model vapour-liquid equilibrium data for pure substances have been correlated. The investigated systems include n-alkanes, 1-alkanols, acetone and carbon dioxide. The results are compared with those obtained by PR (Peng-Robinson), SRK (Soave-Redlich-Kwon) and RM (Riazi-Mansoori) equations of state.
Mousazadeh,M. Hassan (2019). A Molecular-Based Equation of State for Vapour-liquid Equilibrium of Pure Substances. Physical Chemistry Research, 7(1), 95-109. doi: 10.22036/pcr.2018.144626.1523
MLA
Mousazadeh,M. Hassan. "A Molecular-Based Equation of State for Vapour-liquid Equilibrium of Pure Substances", Physical Chemistry Research, 7, 1, 2019, 95-109. doi: 10.22036/pcr.2018.144626.1523
HARVARD
Mousazadeh M. Hassan (2019). 'A Molecular-Based Equation of State for Vapour-liquid Equilibrium of Pure Substances', Physical Chemistry Research, 7(1), pp. 95-109. doi: 10.22036/pcr.2018.144626.1523
CHICAGO
M. Hassan Mousazadeh, "A Molecular-Based Equation of State for Vapour-liquid Equilibrium of Pure Substances," Physical Chemistry Research, 7 1 (2019): 95-109, doi: 10.22036/pcr.2018.144626.1523
VANCOUVER
Mousazadeh M. Hassan A Molecular-Based Equation of State for Vapour-liquid Equilibrium of Pure Substances. PCR, 2019; 7(1): 95-109. doi: 10.22036/pcr.2018.144626.1523
